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This investigation, utilizing the hydrogen borrowing strategy, achieved the functionalization of a -Csp3-H bond within the secondary alcohol substrate, demonstrated by the -arylation reaction with aryl bromides. With a Pd complex catalyst and a ketone co-reactant present, the reaction of secondary alcohols with aryl bromides produced 1,2-diaryl alcohols exhibiting broad substrate scope. The reaction has been further developed with an enantioc