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The high preference for equatorial products seen when using l-glycero-d-gluco donors is also observed when using both d- and l-glycero-d-galacto-configured donors. The d-glycero-d-gluco donor, surprisingly, shows only a mild axial selectivity. The electron-withdrawing thioacetal group, when combined with the specific conformation of the donor's side chain, dictates the selectivity patterns. Subsequent to glycosylation, the removal of the thiophenyl moi
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