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Collectively, the nanoconstruct offers deep tumor permeation and high drug release and broadens the application of the ROS-responsive nanosystem for a successful anticancer effect.2D/3D hybrid perovskites have shown great environmental stability for use as solar cells. Yet insulating organic cation spacers affect the formation of vertically oriented crystalline grains to hamper carrier transport. To date, the selection of cation spacers is limited because crystal growth kinetics should be strictly obeyed. Here, we adopted a mobile-media