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The composite material also showed excellent chromatographic repeatability with the RSDs of the retention time found to be 0.2%-0.6% (n = 1 and the standard addition test in the actual sample proved that it can be used for practical sample analysis. In short, it provided a general way for preparing MOFs-based composites as mixed-mode chromatographic stationary phases, and changed the current status of MOF-based composite materials as single mode chromatographic stationary phases.Herein, we describe a customized approach for facile pr