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The 047-14 m range reveals transparency, a suitable bandgap, and a lower melting point in comparison to LiGaSe2 and LiInSe2. The growth process is more technologically advanced due to the broader homogeneity range displayed in the phase diagram. The two-zone temperature method was used in this work to synthesize the LiGa05In05Se2 polycrystal. A modified Bridgman technique was used to grow LiGa05In05Se2 single crystals (26 mm x 50 mm). The seed crystal, having the lowest thermal expansion coeffic