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Arsenite (As(III)) is more toxic and difficult to remove than arsenate (As(V)). In this study, an S-doped Cu-La bimetallic oxide (S-CuLaO) decorated with metal-organic framework (MOF) composite (S-CuLaO@UIO-66) was synthesized and applied for the adsorption of As(III). The maximum adsorption capacity of As(III) by S-CuLaO@UIO-66 was as high as 171 mg/g, which was much higher compared with other MOF compounds reported to date. The UIO-66 support improved the dispersion and reduced the size of the S-CuLaO particles, which increased the numb