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Fully aromatic, luminescent, and highly robust BNB-doped phenalenyls have been prepared, which are isoelectronic to the phenalenyl cation. B-Fluoromesityl-substitution leads to fluorescence in an extremely narrow range and significant increase in the reduction potential. Detailed theoretical investigations revealed an intramolecular aromaticity switch upon one-electron reduction. Olfactory training (OT) represents a therapeutic option for multiple etiologies of olfactory dysfunction (OD) that also benefits normosmic subjects. In this r