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A lack of exploration concerning the electroluminescence emission of simple and stable zirconium dioxide nanomaterials persists within the realm of ECL sensor research. In the context of the dual-quenching ECL immunosensor, this work featured the introduction of the zirconium dioxide (ZrO2)-titanium dioxide (TiO2)-gold nanoparticle (AuNPs) composite (ZT-Au), a self-enhanced ECL emitter. ZrO2's anodic luminescence in th