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To enhance the internal structure of LiNi05Co02Mn03O2 (NCM523), a modified LiNi05Co02Mn03O2 material was produced via a wet grinding solid-phase method incorporating in situ doping with sodium and chlorine. Eighty cycles at 1°C resulted in an 80.91% capacity retention rate, exceeding the performance of LiNi0.5Co0.2Mn0.3O2 by a remarkable 7000%. Electron microscopy analysis revealed that surface corrosion of LiNi0.5Co0.2Mn0.3O2 was successfully mitigat