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as evidenced in a recent study on umpolung of these reactive intermediates. While our efforts to expand M/X phosphinidenoid complex chemistry are ongoing, we want to emphasize that the development of new reactive intermediates not only improves our understanding of bonding and reactivity but also opens new perspectives in organoelement chemistry.To fabricate high efficiency photoanodes for water oxidation, it is highly required to engineer their nanoporous architecture and interface to improve the charge separation and transport effici