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Structurally diverse aryl chlorides were silylated with sodium silylsilanolate reagents in the presence of a Ni(cod)2 catalyst complexed with a phosphine ligand; PMe2Ph for electron-rich substrates, and PCy2Ph for electron-deficient ones. The mild reaction conditions allowed the silylation of various aryl chlorides including functionalised drug molecules.Prostate-specific antigen (PSA), a glycoprotein that is most likely to cause prostate cancer, has attracted widespread attention in recent years due to its increasing threat to people'

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Amidst the coronavirus disease 2019 (COVID-19) pandemic, there is uncertainty regarding potential lasting impacts on children's health and educational outcomes. Play, a fundamental part of childhood, may be integral to children's health during crises. We undertook a rapid review of the impact of quarantine, isolation and other restrictive environments on play and whether play mitigates adverse effects of such restrictions. Fifteen peer-reviewed studies were identified, spanning hospitals, juvenile and immigration detenti

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Lone workers can often face environments with elevated risks that place their safety at risk, including medical emergencies, violent confrontations and accidents. Lone worker devices offer covert duress triggering and real-time monitoring to mitigate these risks, keeping staff safe when working alone. Learn how a connected lone worker device could protect them. Real-time Communication As lone workers face unique risks that require imm

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Glenoid labrum articular disruption inside a six-year-old child: An instance statement. The efficient conversion of electricity to chemicals is needed to mitigate the intermittency of renewable energy sources. Driving these electrochemical conversions at useful rates requires not only fast electrode kinetics, but also rapid mass and ion transport. However, little is known about the effect of local environments on ionic flows in solid polymer electrolytes. Here, we show that it

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The object of this study is to determine which local wound analgesic option is superior, local anaesthetic infiltration or intercostal nerve block, by combined local anaesthetic agents (0.5% bupivacaine + 2% lidocaine) and to detect which option can best alleviate the post-operative pain management and significantly prolong the time to the first rescue analgesic requirement and the total consumption of opioids in the first post-operative 72 hrs. The medical records of 1458 patients who underwent flank incision procedures by two differen

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FileViewPro is a comprehensive and easy-to-use file viewing solution that allows users to open and explore a wide variety of file types without needing to install multiple programs. Designed to simplify file access, FileViewPro supports hundreds of formats across different categories, including documents, images, media, configuration files, and even web application file types. One of the lesser-known but frequently encountered formats it supports is the ASHX file. These files are typically associated with web servers and ASP.NET appli

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Prioritising epidemiological/clinical aspects of epidemics may have a depoliticising effect and contribute to overlooking socio-economic determinants of the Zika epidemic and issues related to reproductive justice.There is a workforce crisis in NHS general practice (GP). It is estimated that to meet future healthcare needs around 50% of current medical students will need to choose a career in GP. Positive role modelling is an influential factor in medical students' career choice, but denigration of primary care during medical train

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(B6xA/J)F1 and (B6xNOD)F1 HER2 transgenic mice received Ad/E2TM after NK cell depletion, and they produced less HER2 IgG, demonstrating positive regulatory function of NK cells. Depletion of regulatory T cells enhanced response. Using DO QTL analysis, we show that MHC-IB reactive NK cells exert positive influence on the immunity, countering negative regulation by regulatory T cells. This new, to our knowledge, DO F1 platform is a powerful tool for revealing novel immune regulatory mechanisms and for testing new interventional strat

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