https://www.selleckchem.com/pr....oducts/ldc195943-imt
Ethylene complexes of gold(i) have been stabilized by electron-rich, κ2-bound tris(pyrazolyl)borate ligands. Large up-field shifts of olefinic carbon NMR resonances and relatively long C[double bond, length as m-dash]C distances of gold bound ethylene are indicative of significant Au(i) → ethylene π-backbonding relative to the analog supported by a weakly donating ligand, consistent with the computational data.We are reporting the synthesis and structural characterization of a new hexanuclear Cii)/Ciii) complex starting from
처럼
논평
공유하다
