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This work can not only shed new light on TiO2( crystallization, but also provide an effective solution for the rational design of complex TiO2( micro-/nanoarchitectures for desired applications.Efficient reduction of nitrogen to ammonia at a minimal cost would require a recherche catalyst tailored by assimilating the inherent electronic and reactive nature of Single Atom Catalysts (SACs) on heteroatom doped-graphene. A full-scale DFT study accounting for disparate descriptions of atomic orbitals and representation of support, has bee
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