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Valleytronic materials within MA2Z4 structures are now the focus of intense research, driven by the significant potential of enhanced valley spin splitting. Employing first-principles calculations, our analysis predicted six unique 2D Janus MSiGeZ4 (M = Cr and W; Z = N, P, and As) valleytronic materials. For WSiGeZ4 materials (Z = N, P, or As), a valley spin spl
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