https://www.selleckchem.com/pe....ptide/pki-14-22-amid
Nickel has emerged as a desirable substitute for palladium in Sonogashira coupling reactions due to its abundance, less toxicity and high catalytic activity. Ni complexes have been developed to catalyse C(sp)-C(sp2) and C(sp)-C(sp3) Sonogashira couplings that find applications in the synthesis and modifications of biologically relevant molecules. This review focuses on the catalytic potential and mechanistic details of various Ni complexes employed in the Sonogashira coupling. These include homogeneous catalytic sys
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