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The oxygen vacancies in CeO2-B are particularly stable and can be used repeatedly over 30 h without losing activity. The selective PCOs of organic substrates were studied systematically, revealing that the operating mechanisms for UV-illuminated CeO2-B are very different from those for conventional TiO2 photocatalysts. Thus, the present study provides new insights into the design of defect-engineered metal oxides for the development of novel photocatalysts.This research was designed to evaluate the influence of the irradiation process of