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Nanoscale tapioca starch (NTS) was successfully developed by high-speed jet in our previous study. In this study, the adsorption capacity of Cu onto NTS was further discussed. The optimal adsorption conditions (pH, contact time, contact temperature, initial Cu concentration, and adsorbent concentration), adsorption kinetics, isotherms, and thermodynamic were also evaluated. The results showed that NTS exhibited excellent performance in adsorption of Cu , with adsorption capacities of 122.31 mg g for Cu (pH 7, 0.04 g L , 0.2 g L , 313.15 K