https://www.selleckchem.com/
Rigid, freestanding covalent organic framework (COF-1) membranes have been synthesized from 1,4-benzenediboronic acid (BDBA) precursors using two different approaches room temperature solvent-vapour annealing (SVA) and solvothermal annealing (SA). Characterization of films using Fourier-transform infrared (FTIR) spectroscopy, x-ray diffraction (XRD), and various microscopies shows that the films obtained through the two different routes vary in their retained BDBA proportion, crystal size and macroscale morphology. Gas adsorption measurements give specific