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tuberculosis.In this study, we prepared hexagonal and monoclinic phases of La2O2CO3 nanoparticles by different wet preparation methods and investigated their phase-related CO2 behavior through field-emission scanning microscopy, high-resolution transmission electron microscopy, Fourier transform infrared, thermogravimetric analysis, CO2-temperature programmed desorption, and linear sweeping voltammetry of CO2 electrochemical reduction. The monoclinic La2O2CO3 phase was synthesized by a conventional precipitation method via La(OH)CO3 when