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The development of selective and fast optical sensitive chemosensors for the detection and recognition of different cations and anions in a domain is still a challenge in biological, industrial, and environmental fields. Herein, we report a novel approach for the detection and determination of fluoride ion (F-) sensing based on a salen-cobalt metal-organic framework (CII)-MOF). By a simple method, the CII)-MOF was synthesized and characterized using several tools to elucidate the structure and morphology. The photoluminescence (PL) s