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We believe that the technique proposed in this study provides a robust and powerful platform for the fabrication of transparent and flexible TA loudspeakers with excellent self-healing, which can be applied in flexible and wearable acoustic electronics.1,1-Disubstituted styrenes with internal oxygen and nitrogen nucleophiles undergo oxidative fluorocyclization reactions with in situ generated chiral iodine(III)-catalysts. The resulting fluorinated tetrahydrofurans and pyrrolidines contain a tertiary carbon-fluorine stereocenter. Applicat