https://www.selleckchem.com/pr....oducts/shin1-rz-2994
lene (4.41%) and germacrene D (4.23%).The reaction of the rhodium aqua-complex (SRh,RC)-[Cp*Rh(R)-Prophos (OH2)][SbF6]2 [Cp* = C5Me5, Prophos = propane-1,2-diyl-bis(diphenylphosphane)] (1) with trans-4-methylthio-β-nitrostyrene (MTNS) gives two linkage isomers (SRh,RC)-[Cp*Rh(R)-Prophos(κ1O-MTNS)]2+ (3-O) and (SRh,RC)-[Cp*Rh(R)-Prophos(κ1S-MTNS)]2+ (3-S) in which the nitrostyrene binds the metal through one of the oxygen atoms of the nitro group or through the sulfur atom, respectively. Both isomers are in equilibrium in dichlorom
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