https://www.selleckchem.com/pr....oducts/d-lin-mc3-dma
Dissolution of the polyoxometalate (POM) cluster anion H5[PV2Mo10O40] (1; a mixture of positional isomers) in 50% aq H2SO4 dramatically enhances its ability to oxidize methylarenes, while fully retaining the high selectivities typical of this versatile oxidant. To better understand this impressive reactivity, we now provide new information regarding the nature of 1 (115 mM) in 50% (9.4 M) H2SO4. Data from 51V NMR spectroscopy and cyclic voltammetry reveal that as the volume of H2SO4 in water is incrementally increased to 50%, V(V)
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