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The findings not only pave the way to practical rechargeable Li metal batteries but can also be translated to the design of stable metal anodes, e.g., for sodium (Na), magnesium (Mg), and zinc (Zn) batteries.Achieving efficient passivating carrier-selective contacts (PCSCs) plays a critical role in high-performance photovoltaic devices. However, it is still challenging to achieve both an efficient carrier selectivity and high-level passivation in a sole interlayer due to the thickness dependence of contact resistivity and passivation quality. Herein, a ligh