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The internal structure of LiNi05Co02Mn03O2 (NCM523) was enhanced by producing a modified material through a wet grinding solid-phase technique including in situ doping of sodium and chlorine. Eighty cycles at 1°C resulted in an 80.91% capacity retention rate, exceeding the performance of LiNi0.5Co0.2Mn0.3O2 by a remarkable 7000%. Scanning electron microscopy investigations showed that the s