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Anion sensing have attained immense importance as these charged ions are prevailing in agriculture industry and in heavy industry and therefore in the environment around us, chemosensors are commencing to claim several applications as their role is being better perceived day by day. In the current study, coumarin based thiosemicarbazone R-1 (phenyl moiety) and R-2 (benzyl moiety) were synthesized. It was observed that there were variations in the sensing patterns of compound bearing benzyl group, as compared to the simple phenyl group