https://www.selleckchem.com/pr....oducts/relacorilant.
Treatment of [MoCl4(THF)2] with MOtBu (M = Na, Li) does not result in simple metathetic ligand exchange but entails disproportionation with formation of the well-known dinuclear complex [(tBuO)3Mo≡MOtBu)3] and a new paramagnetic compound, [MOtBu)5]. This particular five-coordinate species is the first monomeric, homoleptic, all-oxygen-ligated but non-oxo 4d1 MV) complex known to date; as such, it proves that the dominance of the Mo═O group over (high-valent) molybdenum chemistry can be challenged. [MOtBu)5] was characterize
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