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To our knowledge, this is the first report to identify the involvement of sulfite reductase in selenite reduction under physiological conditions. P. rettgeri HF16 could be a suitable and robust biocatalyst for the bioremediation of selenite, and would accelerate the efficient and economical synthesis of selenium nanoparticles.Dissolved organic matter (DOM) is a crucial controlling factor in mobilizing arsenic. However, direct delineations of DOM regarding both optical properties and molecular signatures were rarely conducted in high-arse