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Commercially available cinchona alkaloids that can catalyze the enantiodivergent fluorination of β-ketodiarylphosphine oxides were developed to construct carbon-fluorine quaternary stereocenters. This protocol features a wide scope of substrates and excellent enantioselectivities, and it is scalable.Cesium lead halide perovskites as ideal photovoltaic and optoelectronics materials have attracted more and more attention. Here, we investigated the structure and electronic properties of halide perovskite CsPbX3 (X = I, Br, Cl) by particle s