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The photophysical studies show that the photoluminescence quantum yields are greatly enhanced in the cyano complexes relative to the chloride precursors, affirming the benefit of strong-field ancillary ligands in the design of blue-phosphorescent complexes. Density functional theory calculations confirm that this enhancement arises from a significant destabilization of the higher-energy ligand-field states in the cyanide complexes relative to the chloride precursors.Starting from lead compound 4, the 1,4-oxazine headgroup was optimized to


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