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84-6.42 ng L-1. The standard deviations for five consecutive extractions of 100 μg L-1 analytes were 3.00-10.20%, while the standard deviation for the extractions of 100 μg L-1 analytes with five different coatings were 5.70-13.80%. The proposed method was applied for the detection of the benzoates in cosmetics, and the recoveries for the spiked benzoates were 82.8-116.8%.Developing efficient and sensitive cytosensing method has great significance for the detection of low abundant circulating tumor cells (CTCs). Electrochemiluminescence