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Thin film composite membranes were fabricated using the interfacial polymerization method with porous organic cages (POCs), namely RCC3 and tren cages. Thin, crosslinked polycage selective layers, with a thickness reaching as little as 95 nanometers, are characterized by high permeance and stringent molecular sieving, enabling precise nanofiltration. Molecular separation, coupled with catalysis, brings about a dual function. Highly catalytically active Pd nanoclusters, approximately 0.7 nanometers in diameter, are used to impregnate the
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