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Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.net.BACKGROUND Hydrazonoyl halides are convenient for the synthesis of arylazothiazoles Results A series of novel arylazothiazoles were efficiently synthesized from the reaction of hydrazonoyl chlorides with 2-(adamantan-2-ylidene)hydrazinecarbothioamide or 2-(ferrocenyl-1-ylidene)hydrazinecarbothioamide in dioxane is used as aprotic solvent, because of its lower toxicity and higher boiling point (101 °C) and triethylamine at reflux. The reaction m