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Co-BTC/10MNC, a catalyst composed of Co-BTC (metal-organic framework) and nitrogen-doped carbon material derived from melamine, facilitated the activation of peroxymonosulfate (PMS). This process yielded both 1O2 and surface-bound sulfate (SO4⁻); however, the surface-bound sulfate was the more significant species. Organic removal's suppression by furfuryl alcohol (FFA) depends on the reacti