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This report places the relationship between ρf and RTIL dielectric response on a quantitative footing and suggests the utility of RTILs for electro-optic applications.Segmented metal-metal heterostructure nanorods/nanowires are very promising for development in photoelectric devices, wearable electronics, biomedicine, and energy storage due to unique surface and interface and adjustable electronic and optical properties. Regretfully, most of the segmented heterojunctions are presently synthesized in organic solvent, and its electronic dy