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Prompt and economical manipulation of molecular behavior is achievable through crystal engineering, a green alternative to organic synthesis. Fluconazole (FLC) and organosulfonate (NDSA-2H) are combined to form the pharmaceutical organic salt (FLC-C) which is then prepared and characterized using the sulfonate-pyridinium supramolecular synthon. The crystallization of a two-component stoichiometric crystal, holding two water molecules, is substantiated by str
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