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In this paper, we fabricate the bulk-like multilayer platinum diselenide (PtSe2) and employ it as saturable absorber (SA) for a passively Q-switched fiber laser operating at 2865 nm for the first time, to the best of our knowledge. The nonlinear optical measurements of the bulk-like multilayer PtSe2 reveal efficient saturable absorption property at around 3 µm showing a modulation depth of 8.54% and a saturation intensity of 0.074 GW/cm2. By introducing the bulk-like PtSe2-SA into the Ho3+/Pr3+ co-doped ZBLAN fiber laser, stable Q-swit