https://www.selleckchem.com/pr....oducts/mpp-dihydroch
Induction of chirality from an achiral assembly system remains a huge challenge related to the origin of life. Here, induction of chirality in a metal-organic framework (MOF) built from achiral precursors has been realized. Assembling achiral H3 BTB ligands and ZnII /CdII clusters leads to a 2D coordination polymer (FJI-H16), while introduction of achiral pyridine into such assembly system leads to a 3D chiral MOF (FJI-H27 (M) or (P)). The driven force for chiral generation has been proved to be a pyridine participated kinet
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