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9% to 98.3%. The above results indicate that the proposed sensor exhibits excellent practical applicability for the rapid and ultrasensitive detection of multiple harmful heavy metals in several environmental water samples, which has potential bright application in protecting the environment and human health.In this study, antibiotic bacteria residues (ABRs) is proposed as a novel green reducing agent and it is found that the reducing agent can realize the efficient recovery of the valuable metals in spent cathode powder (SCP), reduce t