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The Fermi level alignment between electrodes and two-dimensional (2D) materials is significant in characterizing sensors based on their reversibility, response time, sensitivity, and long-term stability. Here, we have demonstrated that the modulation of the Schottky barrier height between the interface of metal (Pd/Au) and multilayered ReSe2 nanoflakes caused the change in the transfer curve (Ids-Vbg) of FETs based devices and rectifying characteristics (Ids-Vds) of the Schottky diodes at various hydrogen concentrations at T = 22 °C, fl